ISOTHIOCYANATO COMPLEXES OF RHENIUM .5. TRANS-BIS(ISOTHIOCYANATO)(METHOXY)(PHENYL-IMIDO)BIS(TRIPHENYLPHOSPHINE)RHENIUM(V)

被引：10
|
作者：
HUBENER, R
ABRAM, U
STRAHLE, J
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷
关键词：
D O I：
10.1107/S0108270195000564
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound consists of well separated molecules of [Re(C6H5N)(CH3O)(NCS)(2)(C18H15P)(2)]. The Re atom is six-coordinate in a distorted octahedral environment. The two triphenylphosphine ligands are arranged trans to each other and there is a methoxy group in the position trans to the phenylimido group. The Re-NPh distance is 1.744(4) Angstrom and the NCS ligands are coordinated via the N atom.
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页码：1284 / 1286
页数：3
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