SYNTHESIS OF POLY(VINYL ALCOHOL) CORE POLYSTYRENE SHELL TYPE MICROSPHERES

被引：12
|
作者：
SAITO, R
OKAMURA, S
ISHIZU, K
机构：
[1] Department of Polymer Chemistry, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152
来源：
POLYMER | 1995年 / 36卷 / 23期
关键词：
CORE-SHELL MORPHOLOGY; MICROSPHERES; POLY(VINYL ALCOHOL-G-STYRENE);
D O I：
10.1016/0032-3861(95)96862-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(vinyl alcohol-g-styrene) graft copolymers with various polystyrene contents (from 9 to 51 mol%) were synthesized. These graft copolymers formed poly(vinyl alcohol) (PVA) core-polystyrene (PS) corona micelles in tetrahydrofuran (THF)-dimethylsulfoxide mixtures when the THF content was from 66 to 69 vol%. The PVA cores of these micelles were crosslinked with terephthal aldehyde (TPA) in solution. When the TPA concentration in relation to vinyl alcohol groups was below 10 mol%, it was possible to hinder intermicelle crosslinking and PVA core-PS shell type microspheres were obtained. The minimum PS shell content of microspheres obtained in this work was 9 mol%.
引用
收藏
页码：4515 / 4520
页数：6
相关论文
共 50 条
  • [1] Synthesis of poly(vinyl alcohol) core-polystyrene shell-type flower microgels
    Saito, R
    Yoshida, S
    Ishizu, K
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 63 (07) : 849 - 854
  • [2] Introduction of silver nano-clusters into poly(vinyl alcohol) core-polystyrene shell type microspheres
    Saito, R
    Okamura, S
    Ishizu, K
    POLYMER, 1996, 37 (23) : 5255 - 5259
  • [3] Synthesis of poly(methacrylic acid) core/polystyrene shell type polymer microspheres
    Saito, R
    Tanaka, S
    Ishizu, K
    POLYMER, 1997, 38 (07) : 1725 - 1729
  • [4] Alginate-poly(vinyl alcohol) core-shell microspheres for lipase immobilization
    De Queiroz, Alvaro A. A.
    Passos, Esdras D.
    De Brito Alves, Sdnei
    Silva, Gerald S.
    Higa, Olga Z.
    Vitolo, Michele
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (02) : 1553 - 1560
  • [5] Alginate-poly(vinyl alcohol) core-shell microspheres for lipase immobilization
    De Queiroz, Álvaro A. A.
    Passes, Esdras D.
    De Brito Alves, Sdnei
    Silva, Gerald S.
    Higa, Olga Z.
    Vítolo, Michele
    Journal of Applied Polymer Science, 2006, 102 (02): : 1553 - 1560
  • [6] Synthesis and mechanical behavior of poly (vinyl alcohol) / poly (vinyl acetate) microspheres
    Ambrosio Tellez, Luisa
    Gisela Veron, Maria
    Cardoso Cuneo, Jorge
    Oscar Prado, Miguel
    POLYMER-PLASTICS TECHNOLOGY AND MATERIALS, 2022, 61 (15): : 1676 - 1690
  • [7] Synthesis of polystyrene microspheres by dispersion polymerization using poly(vinyl alcohol) as a steric stabilizer in aqueous alcohol media
    Hong, Jinho
    Hong, Chang Kook
    Shim, Sang Eun
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 302 (1-3) : 225 - 233
  • [8] Expanded Core/Shell Poly(vinyl acetate)/Poly(vinyl alcohol) Particles for Embolization
    Peixoto, Luciana S.
    Melo, Priamo A.
    Nele, Marcio
    Pinto, Jose Carlos
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2009, 294 (08) : 463 - 471
  • [9] SYNTHESIS OF POLY(VINYL ALCOHOL)-GRAFT-POLYSTYRENE
    TEZUKA, Y
    ARAKI, A
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1993, 194 (10): : 2827 - 2837
  • [10] Preparation of polystyrene-poly(vinyl alcohol) double-shell
    Li, B
    Zhang, ZW
    Wang, CY
    Chen, SF
    LASER INTERACTION WITH MATTER: MEMORIAL TO ACADEMICIAN, NOBEL LAUREATE NG BASOV, 2003, 5228 : 723 - 727
12345