SYNTHESIS OF POLY(VINYL ALCOHOL) CORE POLYSTYRENE SHELL TYPE MICROSPHERES

被引：12
|
作者：
SAITO, R
OKAMURA, S
ISHIZU, K
机构：
[1] Department of Polymer Chemistry, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152
来源：
POLYMER | 1995年 / 36卷 / 23期
关键词：
CORE-SHELL MORPHOLOGY; MICROSPHERES; POLY(VINYL ALCOHOL-G-STYRENE);
D O I：
10.1016/0032-3861(95)96862-3
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(vinyl alcohol-g-styrene) graft copolymers with various polystyrene contents (from 9 to 51 mol%) were synthesized. These graft copolymers formed poly(vinyl alcohol) (PVA) core-polystyrene (PS) corona micelles in tetrahydrofuran (THF)-dimethylsulfoxide mixtures when the THF content was from 66 to 69 vol%. The PVA cores of these micelles were crosslinked with terephthal aldehyde (TPA) in solution. When the TPA concentration in relation to vinyl alcohol groups was below 10 mol%, it was possible to hinder intermicelle crosslinking and PVA core-PS shell type microspheres were obtained. The minimum PS shell content of microspheres obtained in this work was 9 mol%.
引用
收藏
页码：4515 / 4520
页数：6
相关论文
共 50 条
  • [21] Preparation of poly(vinyl acetate)/clay and poly(vinyl acetate)/poly(vinyl alcohol)/clay microspheres
    Hye Min Jung
    Eun Mi Lee
    Byung Chul Ji
    Sung Ok Sohn
    Han Do Ghim
    Hyunju Cho
    Young A Han
    Jin Hyun Choi
    Jae Deuk Yun
    Jeong Hyun Yeum
    Fibers and Polymers, 2006, 7 : 229 - 234
  • [22] Preparation of poly(vinyl acetate)/clay and poly(vinyl acetate)/poly(vinyl alcohol)/clay microspheres
    Jung, Hye Min
    Lee, Eun Mi
    Ji, Byung Chul
    Sohn, Sung Ok
    Ghim, Han Do
    Cho, Hyunju
    Han, Young A.
    Choi, An Hyun
    Yun, Jae Deuk
    Yeum, Jeong Hyun
    FIBERS AND POLYMERS, 2006, 7 (03) : 229 - 234
  • [23] Synthesis and photo physical properties of Au @ Ag (core @ shell) nanoparticles disperse in poly vinyl alcohol matrix
    Santanu Pyne
    Priyanka Sarkar
    Samita Basu
    Gobinda Prasad Sahoo
    Dipak Kumar Bhui
    Harekrishna Bar
    Ajay Misra
    Journal of Nanoparticle Research, 2011, 13 : 1759 - 1767
  • [24] Synthesis and photo physical properties of Au @ Ag (core @ shell) nanoparticles disperse in poly vinyl alcohol matrix
    Pyne, Santanu
    Sarkar, Priyanka
    Basu, Samita
    Sahoo, Gobinda Prasad
    Bhui, Dipak Kumar
    Bar, Harekrishna
    Misra, Ajay
    JOURNAL OF NANOPARTICLE RESEARCH, 2011, 13 (04) : 1759 - 1767
  • [25] Synthesis and characterization of a hydrophilic/hydrophobic IPN composed of poly(vinyl alcohol) and polystyrene
    Tan, YZ
    Xu, MC
    Li, HT
    CHINESE CHEMICAL LETTERS, 2005, 16 (12) : 1597 - 1599
  • [26] Facile synthesis of superhydrophobic TiO2/polystyrene core-shell microspheres
    Chen, Z. M.
    Pan, S. J.
    Yin, H. J.
    Zhang, L. L.
    Ou, E. C.
    Xiong, Y. Q.
    Xu, W. J.
    EXPRESS POLYMER LETTERS, 2011, 5 (01): : 38 - 46
  • [27] Proton-conducting membrane composed of hollow sulfonated polystyrene microspheres, poly(vinyl alcohol) and imidazole
    Wang, Dan
    Pu, Hongting
    Yang, Zheng-Long
    Jiang, F.
    Tang, L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [28] Preparation and characterization of poly(vinyl acetate)/poly(vinyl alcohol)/clay nanocomposite microspheres
    Yeum, Jeong Hyun
    Jung, Hye Min
    Yun, Jae Deuk
    Ji, Byung Chul
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [29] Synthesis of poly(vinyl acetate)-b-polystyrene and poly(vinyl alcohol)-b-polystyrene copolymers by cobalt-mediated radical polymerization
    Bryaskova, Rayna
    Willet, Nicolas
    Debuigne, Antoine
    Jerome, Robert
    Detrembleur, Christophe
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (01) : 81 - 89
  • [30] Stability of immobilized lipase on poly(vinyl alcohol) microspheres
    Oh, Jae Min
    Lee, Dong Hwan
    Song, Yoon Seok
    Lee, Se Geun
    Kim, Seung Wook
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2007, 13 (03) : 429 - 433
12345