Poly[(acetonitrile-kappa N)-mu(3)-thiocyanato-kappa N-3:S:S-mu(2)-thiocyanato-kappa N-2:S-cadmium]

被引:0
|
作者
Reinert, Thorben [1 ]
Jess, Inke [1 ]
Naether, Christian [1 ]
机构
[1] Christian Albrechts Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24098 Kiel, Germany
关键词
D O I
10.1107/S1600536813015870
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Cd(NCS)(2)(CH3CN)](n), consists of one Cd-II cation, two thiocyanate anions and one acetonitrile ligand, all in general positions. The Cd II cation is coordinated by three N atoms of two thiocyanate anions and one acetonitrile ligand, as well as three S atoms of symmetry-related thiocyanate anions within a slightly distorted octahedral coordination environment. The Cd II cations are linked by mu-1,3(N, S) and mu-1,1,3(S, S, N) thiocyanate anions into layers that are located in the ab plane.
引用
收藏
页码:M398 / +
页数:6
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