SYNTHESIS OF 1,3,5-TRIAMINO-2,4,6-TRIPHENYLBENZENE AND ITS REACTION WITH PICRYL HALIDES

被引：0

作者：

ZIERER, D ^{[1
]}

DULOG, L ^{[1
]}

机构：

[1] UNIV STUTTGART,INST TECH CHEM 2,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY

来源：

LIEBIGS ANNALEN DER CHEMIE | 1993年 / 06期

关键词：

ULLMANN SYNTHESIS; TERPHENYLS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

',4',6'-Trinitro-5'-phenyl-1,1':3',1''-terphenyl (5) was synthesized by Ullmann reaction of 1,3,5-trichloro-2,4,6-trinitrobenzene (3) with iodobenzene and copper powder in the presence of NN-dimethylformamide. Reduction of 5 with tin/tin(II) chloride in a mixture of hydrochloric and acetic acid yields 2',4',6'-triamino-5'-phenyl-1,1':3',1''-terphenyl (6). By reaction of this symmetric benzenetriamine with picryl chloride and fluoride in different media, but utmost two of the three amino groups were converted into picrylamide groups to 7 and 8.

引用

页码：691 / 693

页数：3

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