SYNTHESIS OF 1,3,5-TRIAMINO-2,4,6-TRIPHENYLBENZENE AND ITS REACTION WITH PICRYL HALIDES

被引：0
|
作者：
ZIERER, D [1 ]
DULOG, L [1 ]
机构：
[1] UNIV STUTTGART,INST TECH CHEM 2,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY
来源：
LIEBIGS ANNALEN DER CHEMIE | 1993年 / 06期
关键词：
ULLMANN SYNTHESIS; TERPHENYLS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
',4',6'-Trinitro-5'-phenyl-1,1':3',1''-terphenyl (5) was synthesized by Ullmann reaction of 1,3,5-trichloro-2,4,6-trinitrobenzene (3) with iodobenzene and copper powder in the presence of NN-dimethylformamide. Reduction of 5 with tin/tin(II) chloride in a mixture of hydrochloric and acetic acid yields 2',4',6'-triamino-5'-phenyl-1,1':3',1''-terphenyl (6). By reaction of this symmetric benzenetriamine with picryl chloride and fluoride in different media, but utmost two of the three amino groups were converted into picrylamide groups to 7 and 8.
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页码：691 / 693
页数：3
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