THE NU-5 BAND OF C-7

被引：36

作者：

HEATH, JR

VANORDEN, A

KUO, E

SAYKALLY, RJ

机构：

[1] Department of Chemistry, University of California, Berkeley

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(91)80096-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Twenty-four rotational lines associated with the nu-5 (sigma-u) antisymmetric stretch vibration of C-7 have been measured by high resolution diode laser absorption spectroscopy of a supersonic carbon cluster beam. A simultaneous fit of spectra connecting the ground state with upsilon = 1 of nu-4 (J.R. Heath et al., Science 249 (1990) 895, J.R. Heath and R.J. Saykally, J. Chem. Phys. 94 (1991) 1724) and nu-5 produces the following molecular constants for the nu-5 state (in cm-1): nu-5= 1898.3758(8), B' =0.030556(15), D'= -0.16(11) X 10(-7), H'= -0.44(31) x 10(-11).

引用

页码：17 / 20

页数：4

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