UNUSUAL FINE-STRUCTURE OF NU-5 VIBRONIC BAND IN ABSORBENCY OF CONDUCTING TCNQ LB FILMS OBTAINED BY THE HOMODOPING STRATEGY

被引：2

作者：

YARTSEV, VM ^{[1
]}

BOURGOIN, JP ^{[1
]}

DELHAES, P ^{[1
]}

VANDEVYVER, M ^{[1
]}

BARRAUD, A ^{[1
]}

机构：

[1] CENS,CEA,SCM,F-91191 GIF SUR YVETTE,FRANCE

来源：

SYNTHETIC METALS | 1993年 / 57卷 / 01期

关键词：

D O I：

10.1016/0379-6779(93)90516-Y

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Experimental IR properties of conducting (ODS-TCNQ)0,33(TCNQC18)0,66.LB films are presented and discussed within the frame of the electron-vibration coupling model of Rice, extended to take into account the modifications induced by grafting an alkyl chain to TCNQ molecule. Quite good theoretical fit of experimental spectra (including unusual fine structure of a(g)nu5 vibronic band) indicates that, inside the layer, an energy transfer takes place between the electroactive part and the alkyl chain via a two step coupling process.

引用

页码：3801 / 3806

页数：6

共 2 条

[1] SPECTROSCOPIC AND ELECTRONIC-PROPERTIES OF CONDUCTING TCNQ LB FILMS ISSUED FROM A HOMODOPING STRATEGY
FICHET, O
BOURGOIN, JP
DELHAES, P
DESBAT, B
GIONIS, V
YARTSEV, V
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1993, 234 : 179 - 186
[2] FINE-STRUCTURE IN THE [(2-TAU-3+NU-3)]-1NU-1] VIBRONIC BAND IN PUF6
KIM, KC
KROHN, BJ
BRIESMEISTER, R
RABIDEAU, S
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (03): : 1538 - 1539

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