KINETIC FEATURES OF AZOXYBENZENE HYDROGENATION IN AQUEOUS 2-PROPANOL SOLUTIONS ON SKELETAL NICKEL WITH ADDITIVES OF ACID AND BASE

被引:0
|
作者
Nguyen Thi Thu Ha [1 ]
Merkin, A. A. [1 ]
Lefedova, O. V. [1 ]
机构
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
关键词
azoxybenzene; hydrogenation; skeletal nickel;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It was experimentally shown that the addition of sodium hydroxide to aqueous 2-propanol solutions lead to the increase in observed rate of azoxy-group reduction, whereas ddition of acetic acid cause its decrease. The change in the reaction rate of azoxybenzen hydrogenation on skeletal nickel in aqueous 2-propanol solutions in the presence of additives was established to agree with the change in limiting adsorption values of atomic adsorbed hydrogen.
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页码:79 / +
页数:4
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