KINETIC FEATURES OF AZOXYBENZENE HYDROGENATION IN AQUEOUS 2-PROPANOL SOLUTIONS ON SKELETAL NICKEL WITH ADDITIVES OF ACID AND BASE

被引：0
|
作者：
Nguyen Thi Thu Ha [1 ]
Merkin, A. A. [1 ]
Lefedova, O. V. [1 ]
机构：
[1] Ivanovo State Univ Chem Technol, Ivanovo, Russia
来源：
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2012年 / 55卷 / 10期
关键词：
azoxybenzene; hydrogenation; skeletal nickel;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It was experimentally shown that the addition of sodium hydroxide to aqueous 2-propanol solutions lead to the increase in observed rate of azoxy-group reduction, whereas ddition of acetic acid cause its decrease. The change in the reaction rate of azoxybenzen hydrogenation on skeletal nickel in aqueous 2-propanol solutions in the presence of additives was established to agree with the change in limiting adsorption values of atomic adsorbed hydrogen.
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页码：79 / +
页数：4
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