SOME UNUSUAL ORGANO-ZINC AND ORGANO-MERCURY COMPOUNDS - THE CRYSTAL-STRUCTURES OF THE COMPOUNDS [(HOME2SI)(ME3SI)2C]2ZN, [(MEOME2SI)(ME3SI)2C]2ZN, AND [(MEOME2SI)(ME3SI)2C]2HG

被引：25

作者：

AIGBIRHIO, FI

ALJUAID, SS

EABORN, C

HABTEMARIAM, A

HITCHCOCK, PB

SMITH, JD

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton, BN1

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 405卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)86267-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of the novel mercurial [(MeOMe2Si)(Me3Si)2C]2Hg is described. X-ray diffraction studies show that the molecules of this compound and its zinc analogue are centrosymmetric (and the C-M-C linkage thus linear), but in the former the OMe group is directed away from the metal atom whereas in the latter it lies in towards the metal, with an O...Zn distance of 2.93 angstrom. In crystals of [(HOMe2Si)(Me3Si)2C]2Zn there is hydrogen bonding between the two oxygen atoms within each molecule, and hydrogen bonding between two molecules to give discrete dimers. Because of the hydrogen bonding the C-Zn-C linkage is slightly bent (the angle is 175.9(1)-degrees), and the geometries of the two (HOMe2Si)(Me3Si)2C groups are significantly different.

引用

页码：149 / 160

页数：12

共 50 条

[11] Manganese and cesium derivatives of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C.: Crystal structures of Li(THF)2.75(Et2O)0.25(μ-Cl)-MnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C and. (C6H6)3CsC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CCs(C6H6)3
Eaborn, C
Hitchcock, PB
Smith, JD
Zhang, SB
Clegg, W
Izod, K
O'Shaughnessy, P
ORGANOMETALLICS, 2000, 19 (06) : 1190 - 1193
[12] PREPARATION AND REACTIONS OF DIFUNCTIONAL STERICALLY HINDERED ORGANO-SILICON COMPOUNDS OF THE TYPE (ME3SI)2C(SIME2X)(SIME2Y)
EABORN, C
REED, DE
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (10): : 1687 - 1693
[13] SYNTHESIS, STRUCTURE AND REACTIONS OF (ME3SI)2C(H)CB10H11.SME2
ERNEST, RL
SNEDDON, LG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 164 - INOR
[14] PREPARATION AND CRYSTAL-STRUCTURES OF THE CROWDED ORGANOTIN FLUORIDES (PHME2SI)3CSNME2F, (ME3SI)3CSNME2F, AND (ME3SI)3CSNPH2F
ALJUAID, SS
DHAHER, SM
EABORN, C
HITCHCOCK, PB
SMITH, JD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) : 117 - 127
[15] From 2,4-diphospha-3-thia- and -3-selenapentadienes [(Me3Si)2C=P]2E to heteronorbornane cage compounds
du Mont, Wolf-W.
Gust, Thorsten
Mahnke, Jens
Birzoi, Roxana M.
Barra, Lisa
Bugnariu, Delia
Ruthe, Frank
Wismach, Cathleen
Jones, Peter G.
Karaghiosoff, Konstantin
Nyulaszi, Laszlo
Benko, Zoltan
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (45) : 8682 - 8685
[16] Organotin compounds containing a bulky (Me3Si)3C or related ligand.: Crystal structures of {(Me3Si)3CMe(O2NO)Sn}2O, (PhMe2Si)3CSnMeCl2 and (PhMe2Si)3CSnCl3
Al-Juaid, SS
Al-Rawi, M
Eaborn, C
Hitchcock, PB
Smith, JD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 564 (1-2) : 215 - 226
[17] Synthesis and characterization of tris(trimethylsilyl)methylaluminum chalcogenides [RAl(μ3-E)]4 (R = (Me3Si)3C; E = Se, Te) and 1-azaallylgallium chalcogenides [R′Ga(μ2-E)]2 (R′ = (Me3Si)2C(Ph)C(Me3Si)N; E = S, Se, Te)
Klimek, KS
Prust, J
Roesky, HW
Noltemeyer, M
Schmidt, HG
ORGANOMETALLICS, 2001, 20 (10) : 2047 - 2051
[18] Preparation and structural characterization of bis[tris(trimethylsilyl)germyl]zinc, [(Me3Si)3Ge]2Zn
Nanjo, M
Oda, T
Mochida, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (06) : 1261 - 1264
[19] THE NATURE OF THE ANCHIMERIC ASSISTANCE BY THE ACETOXY GROUP IN SOLVOLYSIS OF (ME3SI)2C(SIME2OCOME)(SIME2CL)
EABORN, C
LICKISS, PD
TAYLOR, AD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 338 (02) : C27 - C29
[20] Preparation and structural characterisation of the cation-π complexes [{(Me3Si)2NK} • (tBu-C6H5)]2 and [{(Me3Si)2NK} • (Me3-C6H3)]2
Randazzo, John B.
Morris, J. Jacob
Henderson, Kenneth W.
MAIN GROUP CHEMISTRY, 2006, 5 (03) : 215 - 220

← 1 2 3 4 5 →