Preparation and structural characterization of bis[tris(trimethylsilyl)germyl]zinc, [(Me3Si)3Ge]2Zn

被引：6

作者：

Nanjo, M ^{[1
]}

Oda, T ^{[1
]}

Mochida, K ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 06期

关键词：

D O I：

10.1246/bcsj.76.1261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis[tris(trimethylsilyl)germyl]zinc, [(Me3Si)(3)Ge](2)Zn, was prepared by the reaction of [tris(trimethylsilyl)germyl]-lithium, (Me3Si)(3)GeLi(thf), with zinc chloride, ZnCl2, and by the reaction of tris(trimethylsilyl)germane, (Me3Si)(3)GeH, with diethylzinc, Et2Zn. The molecular structure of [(Me3Si)(3)Ge](2)Zn was determined by spectroscopic and X-ray diffraction methods. In [(Me3Si)(3)Ge](2)Zn, the two tris(trimethylsilyl)germyl ligands, (Me3Si)(3)Ge, are bonded in a linear fashion to the zinc atom and are staggered with respect to each other. The reactions of bis(germyl)zinc with substrates were also examined.

引用

页码：1261 / 1264

页数：4

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