Preparation and characterization of tris(trimethylsilyl)germylzinc chloride and bis[tris(trimethylsilyl)germyl]zinc

被引：11

作者：

Nanjo, M ^{[1
]}

Oda, T ^{[1
]}

Mochida, K ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 01期

关键词：

D O I：

10.1246/cl.2002.108

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structure of (Me3Si)(3)GeZnCl (1) has been determined by single-crystal X-ray diffraction. The germylzinc chloride 1 has a dimeric structure consisting of two mu-Cl atoms. The compound 1 reacted with (Me3Si)(3)GeLi in diethyl ether to give [(Me3Si)(3)Ge](2)Zn (2), quantitatively. The structure of bis(germyl)zinc 2 has been also elucidated by X-ray diffraction.

引用

页码：108 / 109

页数：2

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