SYNTHESIS AND CHARACTERIZATION OF CIS-DIOXOMOLYBDENUM(VI) COMPLEX OF THE SCHIFF-BASE SALICYLALDEHYDE ISONICOYHYDRAZONE (SAIH) AND THE CRYSTAL-STRUCTURE OF [MOO2(ORTHO-C6H4CH=NN=COC5H4N)CH3OH]

被引：0

作者：

ZHAI, YL ^{[1
]}

XU, XX ^{[1
]}

WANG, X ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

POLYHEDRON | 1992年 / 11卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[MoO2(butanediolato)2.2(butanediol)] reacts with the Schiff base SAIH in methanol to afford the title complex which has been characterized by elemental analysis, IR and electronic spectroscopy and TGA. The single crystal X-ray structure of the complex reveals that the molecule possesses the usual cis-MoO2(2+) core and that the ligand SAIH is present as a tridentate donor coordinating through ONO, which forms one five-membered ring and one six-membered ring. The sixth coordination site around Mo is occupied by a methanol molecule, giving the molybdenum a distorted octahedral configuration.

引用

页码：415 / 418

页数：4

共 50 条

[31] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF ME(2)NC(6)H(4)CH=CHC5H4N(C2H5)(+)[LA(TTA)(4)](-)(TTA=ALPHA-THENOYLTRIFLUOROACETONATO)
WANG, KZ
HUANG, CH
XU, GX
WANG, RJ
POLYHEDRON, 1995, 14 (23-24) : 3669 - 3673
[32] Crystal structure of 6-diethylamino-1,4-dihydro-5-methyl-4-oxo-3-phenyl-1-(4-toluoyl)pyridazine, C4N2O(CH3)(COC6H4CH3(N(C2H5)2(C6H5)
Peters, K
Peters, EM
Feineis, E
Christl, M
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (04): : 769 - 770
[33] Synthesis, Spectroscopic Characterization and Crystal Structure of a New Acetyl phosphorylamidate P(O)[NHC(O)C6H4(4-NO2)][N(CH(CH3)2)(CH2C6H5)]2
Mehrdad Pourayoubi
Fahimeh Sabbaghi
Journal of Chemical Crystallography, 2009, 39 : 874 - 880
[34] Synthesis, crystal structure and magnetic properties of the tetranuclear complex [Ni-4(OCH3)(4)(dbm)(4)(CH3OH)(4)](2)(C2H5)(2)O
ElFallah, MS
Rentschler, E
Caneschi, A
Gatteschi, D
INORGANICA CHIMICA ACTA, 1996, 247 (02) : 231 - 235
[35] Synthesis, Spectroscopic Characterization and Crystal Structure of a New Acetyl phosphorylamidate P(O)[NHC(O)C6H4(4-NO2)][N(CH(CH3)2)(CH2C6H5)]2
Pourayoubi, Mehrdad
Sabbaghi, Fahimeh
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (12) : 874 - 880
[36] CRYSTAL AND MOLECULAR-STRUCTURES OF ETA-4-OLEFIN CARBENE COMPLEX [(ETA-4-]C6H5CH=CH-)-CH(C6H4CH3-]M)N(C6H5) C(OC2H5)=]FE(CO)2.1/2C6H5.CH3
ZHANG, ZY
TANG, YQ
YIN, JG
CHEN, JB
XU, WH
KEXUE TONGBAO, 1988, 33 (17): : 1431 - 1435
[37] Hydrothermal Synthesis,Crystal Structure and Thermal Stability Properties of the Complex [Cd2(phen)2(C14H11O3)4(CH3CH2OH)]·(CH3OH)·(H2O)
李昶红
谢和平
谭雄文
杨颖群
李薇
结构化学, 2010, 29 (09) : 1317 - 1320
[38] Synthesis and Crystal Structure of[C6H5CH2C5H4ErCl2（THF）3]·THF
Gao Fu-Xing
Wei Ge-Cheng
Jin Zhong-Sheng
Chen Wen-Qi (Changchun Institute of Applied Chemistry
结构化学, 1994, (04) : 247 - 251
[39] REACTION OF FOLDED ACETATE-BRIDGED ORTHO-PALLADATED COMPLEXES WITH CH2CL2 - CRYSTAL-STRUCTURE OF [(PD(C6H5-CH2-N=C-(COC6H5)-C6H4)(MU-CL))2]
NAVARRORANNINGER, C
LOPEZSOLERA, I
ALVAREZVALDES, A
RODRIGUEZJH
MASAGUER, JR
GARCIARUANO, JL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 476 (01) : 19 - 24
[40] Synthesis and characterization of 1,1′-bis[(N-methyl-N-phenyl)aminomethyl(ethyl)]ferrocenes.: Crystal structures of [Fe{(η5-C5H4)-C(C6H5)=N-CH2C6H4CH3-4}2] and 2[Fe{(η5-C5H4)-CH2N(CH3)-C6H4OCH3-4}2] • 1/4H2O
Wang, Hong-Xing
Gao, Ren-Qing
Yang, Xiao-Li
Wan, Li
Wu, Hong-Fei
Gieng, Feng-Ying
Jin, Rong
POLYHEDRON, 2007, 26 (05) : 1037 - 1044

← 1 2 3 4 5 →