SYNTHESIS AND CHARACTERIZATION OF CIS-DIOXOMOLYBDENUM(VI) COMPLEX OF THE SCHIFF-BASE SALICYLALDEHYDE ISONICOYHYDRAZONE (SAIH) AND THE CRYSTAL-STRUCTURE OF [MOO2(ORTHO-C6H4CH=NN=COC5H4N)CH3OH]

被引：0

作者：

ZHAI, YL ^{[1
]}

XU, XX ^{[1
]}

WANG, X ^{[1
]}

机构：

[1] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA

来源：

POLYHEDRON | 1992年 / 11卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[MoO2(butanediolato)2.2(butanediol)] reacts with the Schiff base SAIH in methanol to afford the title complex which has been characterized by elemental analysis, IR and electronic spectroscopy and TGA. The single crystal X-ray structure of the complex reveals that the molecule possesses the usual cis-MoO2(2+) core and that the ligand SAIH is present as a tridentate donor coordinating through ONO, which forms one five-membered ring and one six-membered ring. The sixth coordination site around Mo is occupied by a methanol molecule, giving the molybdenum a distorted octahedral configuration.

引用

页码：415 / 418

页数：4

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