Crystal structure of di-mu-hvdroxido-bis{aqua[ethyl(1,10-phenanthrolin-3-yl)pnospnonato-kappa N-2,N ']-copper(II)} heptahydrate

被引：0
|
作者：
Mitrofanov, Alexander Yu [1 ]
Rousselin, Yoann [2 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, GSP 3, Moscow 119991, Russia
[2] Univ Bourgogne Franche Comte, ICMUB, UMR CNRS 6302, 9 Ave Alain Savary, F-21078 Dijon, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷
基金：
俄罗斯基础研究基金会;
关键词：
crystal structure; ethyl 1,10-phenanthrolin-3-yl-phosphonate; copper(II); hydrogen bonding;
D O I：
10.1107/S2056989018015724
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu-2(OH)(2){C12H7N2(PO3C2H5)}(2)(H2O)(2)]center dot 7H(2)O, two Cu2+ cations are bridged by two hydroxide groups, forming a centrosymmetric binuclear complex. Each Cu2+ cation is further coordinated by the N atoms of a bidentate ethyl (1,10-phenanthrolin-3-yl)phosphonate anion and a water molecule in a square-pyramidal geometry. In the crystal, a network of O-H center dot center dot center dot O hydrogen bonds involving the P(O)(O-)(OEt) groups, bridging hydroxyl groups, coordinated and uncoordinated water molecules generates a three-dimensional supramolecular structure. The ethyl group exhibits disorder and was modelled over three sites with occupancies of 0.455, 0.384 and 0.161.
引用
收藏
页码：1751 / +
页数：11
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