Crystal structure of di-mu-hvdroxido-bis{aqua[ethyl(1,10-phenanthrolin-3-yl)pnospnonato-kappa N-2,N ']-copper(II)} heptahydrate

被引：0

作者：

Mitrofanov, Alexander Yu ^{[1
]}

Rousselin, Yoann ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, GSP 3, Moscow 119991, Russia

[2] Univ Bourgogne Franche Comte, ICMUB, UMR CNRS 6302, 9 Ave Alain Savary, F-21078 Dijon, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷

基金：

俄罗斯基础研究基金会;

关键词：

crystal structure; ethyl 1,10-phenanthrolin-3-yl-phosphonate; copper(II); hydrogen bonding;

D O I：

10.1107/S2056989018015724

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu-2(OH)(2){C12H7N2(PO3C2H5)}(2)(H2O)(2)]center dot 7H(2)O, two Cu2+ cations are bridged by two hydroxide groups, forming a centrosymmetric binuclear complex. Each Cu2+ cation is further coordinated by the N atoms of a bidentate ethyl (1,10-phenanthrolin-3-yl)phosphonate anion and a water molecule in a square-pyramidal geometry. In the crystal, a network of O-H center dot center dot center dot O hydrogen bonds involving the P(O)(O-)(OEt) groups, bridging hydroxyl groups, coordinated and uncoordinated water molecules generates a three-dimensional supramolecular structure. The ethyl group exhibits disorder and was modelled over three sites with occupancies of 0.455, 0.384 and 0.161.

引用

页码：1751 / +

页数：11

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