1-Ethyl-4 '-(1H-indol-3-ylcarbonyl)-1 '-methyl-2,2 ''-dioxodispiro[indoline-3,2 '-pyrrolidine-3 ',3 ''-indoline]-4 ' carbonitrile dimethyl sulfoxide monosolvate

被引:2
|
作者
Inglebert, S. Antony [1 ]
Arun, Yuvaraj [2 ]
Sethusankar, K. [3 ]
Perumal, Paramasivam T. [2 ]
机构
[1] Sri Ram Engn Coll, Chennai 602024, Tamil Nadu, India
[2] Cent Leather Res Inst, Organ Chem Div, Chennai 600020, Tamil Nadu, India
[3] RKM Vivekananda Coll Autonomous, Dept Phys, Chennai 600004, Tamil Nadu, India
关键词
data-toparameter ratio = 11.9; disorder in solvent or counterion; meanω(C - C) = 0.004 A °; Rfactor = 0.042; single-crystal X-ray study; T = 295 K; wRfactor = 0.120;
D O I
10.1107/S1600536813020485
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C31H25N5O3 center dot C2H6OS, the three indole/indoline units are all essentially planar with maximum deviations of 0.0172 (3), 0.053 (2) and 0.07 (2) angstrom. The pyrrolidine ring adopts an envelope conformation with the C atoms bearing the 1-ethyl-2-oxoindole substituent (in which the five-membered ring adopts a twisted conformation) as the flap. The dimethyl sulfoxide solvent molecule is disordered over two positions, with an occupancy factor ratio of 0.871 (4): 0.129 (4). The solvent components are linked to the heterocyclic molecule via C-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds. In the crystal, the solvent components are linked to the heterocyclic molecule via C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions, forming R-2(2) (10) ring motifs. The molecules are further connected into a chain along the a-axis direction via NH center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:O1328 / +
页数:13
相关论文
共 50 条
  • [41] 5-Chloro-5 ''-(4-chlorobenzylidene)4 '-(4-chlorophenyl)-1 ',100-dimethyldispiro[indoline-3 ',2 ''-pyrrolidine-3 ',3 '' piperidine]-2,400-dione
    Farag, I. S. Ahmed
    Girgis, Adel S.
    Ramadan, A. A.
    Moustafa, A. M.
    Mabied, Ahmed F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O379 - +
  • [42] 1'-Methyl-4'- phenyldispiro[chromane2',3"-pyrrolidine-2',2"-indoline]-2,2"-dione
    Ganapathy, Jagadeesan
    Damodharan, Kannan
    Manickam, Bakthadoss
    Sanmargam, Aravindhan
    Krishnasamy, Gunasekaran
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O915 - U3493
  • [43] 1-(1H-indol-3-ylcarbonyl)-N-(4-methoxybenzyl)formamide
    Sonar, VN
    Parkin, S
    Crooks, PA
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 : O153 - O154
  • [44] 3′-(4-Chlorobenzoyl)-4′-(4-chlorophenyl)-1′-methylspiro[indoline-3,2′-pyrrolidin]-2-one
    Srinivasan, T.
    Suhitha, S.
    Purushothaman, S.
    Raghunathan, R.
    Velmurugan, D.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3128 - U2263
  • [45] Synthesis of some new spiro[indoline-3,2′-(1′,2′,3′,4′-tetrahydroquinoline)]-2,4′-dione derivatives
    Al-Thebeiti, MS
    HETEROCYCLES, 1998, 48 (01) : 145 - 150
  • [46] An Efficient Synthesis of 6′-methyl-1′H-spiro[indoline-3,4′-pyrimidine]-2,2′(3′H)-dione Derivatives
    Gao, Lijiu
    Qin, Yaqi
    Yu, Qiuyu
    Ling, Zhi
    Xu, Zhongyun
    Rong, Liangce
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (06) : 3258 - 3264
  • [47] 1′-Methyl-4′-phenyldispiro[indan-2,2′-pyrrolidine-3′,2"-indan]-1,3,1"-trione
    Wei, Ang Chee
    Ali, Mohamed Ashraf
    Choon, Tan Soo
    Quah, Ching Kheng
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2383 - U713
  • [48] Crystal structure of ethyl 1 ',1 ''-dimethyl-2 '',3-dioxo-3H-dispiro[benzo[b]thiophene-2,3 '-pyrrolidine-2 ',3 ''-indoline]-4 '-carboxylate
    Savithri, M. P.
    Suresh, M.
    Raghunathan, R.
    Raja, R.
    SubbiahPandi, A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O142 - +
  • [49] 3-Benzylidene-1′-methyl-4′-phenylcyclohexanespiro3′-pyrrolidine-2′-spiro-3"-indoline-2,2"-dione
    Jeyabharathi, A
    Ponnuswamy, MN
    Raj, AA
    Raghunathan, R
    Razak, IA
    Usman, A
    Chantrapromma, S
    Fun, HK
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : o901 - O903
  • [50] 4′-(4-methoxybenzoyl)-1′-methyl acenaphthene-1-spiro-2′-pyrrolidine-3′-spiro-3"-1H-indole-2,2"(1H,3"H)-dione hemihydrate
    Govind, MM
    Selvanayagam, S
    Velmurugan, D
    Ravikumar, K
    Sureshbabu, AR
    Raghunathan, R
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O1003 - O1005