1-Ethyl-4 '-(1H-indol-3-ylcarbonyl)-1 '-methyl-2,2 ''-dioxodispiro[indoline-3,2 '-pyrrolidine-3 ',3 ''-indoline]-4 ' carbonitrile dimethyl sulfoxide monosolvate

被引:2
|
作者
Inglebert, S. Antony [1 ]
Arun, Yuvaraj [2 ]
Sethusankar, K. [3 ]
Perumal, Paramasivam T. [2 ]
机构
[1] Sri Ram Engn Coll, Chennai 602024, Tamil Nadu, India
[2] Cent Leather Res Inst, Organ Chem Div, Chennai 600020, Tamil Nadu, India
[3] RKM Vivekananda Coll Autonomous, Dept Phys, Chennai 600004, Tamil Nadu, India
关键词
data-toparameter ratio = 11.9; disorder in solvent or counterion; meanω(C - C) = 0.004 A °; Rfactor = 0.042; single-crystal X-ray study; T = 295 K; wRfactor = 0.120;
D O I
10.1107/S1600536813020485
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C31H25N5O3 center dot C2H6OS, the three indole/indoline units are all essentially planar with maximum deviations of 0.0172 (3), 0.053 (2) and 0.07 (2) angstrom. The pyrrolidine ring adopts an envelope conformation with the C atoms bearing the 1-ethyl-2-oxoindole substituent (in which the five-membered ring adopts a twisted conformation) as the flap. The dimethyl sulfoxide solvent molecule is disordered over two positions, with an occupancy factor ratio of 0.871 (4): 0.129 (4). The solvent components are linked to the heterocyclic molecule via C-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen bonds. In the crystal, the solvent components are linked to the heterocyclic molecule via C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions, forming R-2(2) (10) ring motifs. The molecules are further connected into a chain along the a-axis direction via NH center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:O1328 / +
页数:13
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