SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE ANALYSIS OF A NOVEL MU-4-OXO UNDECA-OSMIUM CARBONYL CLUSTER [OS11(MU-4-O)3(CO)30]

被引：17
|
作者：
INGHAM, SL
LEWIS, J
RAITHBY, PR
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期
关键词：
D O I：
10.1039/c39930000166
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first example of an osmium cluster containing mu4-oxo groups, [Os11(mu4-O)3(CO)30] 1, has been obtained from the vacuum pyrolysis of [Os3H(CO)10(mu-OH)], and has been shown by X-ray crystallography to contain a tri-edge bridged, bicapped trigonal prismatic metal core.
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页码：166 / 167
页数：2
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