Synthesis and X-ray structure of the hexaosmium carbonyl cluster containing a mu(4)-eta(3)-CO2 group

被引:5
|
作者
Ho, WGY [1 ]
Wong, WT [1 ]
机构
[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG
关键词
D O I
10.1016/0277-5387(95)00228-K
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of [Os-3(mu-H)(CO)(11)](-) (1) with Cu-II salts in dichloromethane gave the yellow cluster [Os-3(mu-H)(CO)(10)(mu(4)-eta(3)-CO2)Os-3(mu-H)(CO)(10)] (2) amongst several other known products; 2 has been fully characterized by both spectroscopic and crystallographic methods.
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页码:165 / 167
页数:3
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