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Synthesis and X-ray structure of the hexaosmium carbonyl cluster containing a mu(4)-eta(3)-CO2 group
被引:5
|作者:
Ho, WGY
[1
]
Wong, WT
[1
]
机构:
[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG
来源:
关键词:
D O I:
10.1016/0277-5387(95)00228-K
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The reaction of [Os-3(mu-H)(CO)(11)](-) (1) with Cu-II salts in dichloromethane gave the yellow cluster [Os-3(mu-H)(CO)(10)(mu(4)-eta(3)-CO2)Os-3(mu-H)(CO)(10)] (2) amongst several other known products; 2 has been fully characterized by both spectroscopic and crystallographic methods.
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页码:165 / 167
页数:3
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