SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE ANALYSIS OF A NOVEL MU-4-OXO UNDECA-OSMIUM CARBONYL CLUSTER [OS11(MU-4-O)3(CO)30]

被引：17

作者：

INGHAM, SL

LEWIS, J

RAITHBY, PR

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of an osmium cluster containing mu4-oxo groups, [Os11(mu4-O)3(CO)30] 1, has been obtained from the vacuum pyrolysis of [Os3H(CO)10(mu-OH)], and has been shown by X-ray crystallography to contain a tri-edge bridged, bicapped trigonal prismatic metal core.

引用

页码：166 / 167

页数：2

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