ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES BY CHIRAL TITANIUM SCHIFFS BASE COMPLEXES

被引:117
|
作者
HAYASHI, M [1 ]
MIYAMOTO, Y [1 ]
INOUE, T [1 ]
OGUNI, N [1 ]
机构
[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN
关键词
D O I
10.1039/c39910001752
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The complexes formed between titanium tetraalkoxide and chiral Schiff's bases make excellent catalysts for enantioselective trimethylsilylcyanation of aldehydes to optically active cyanohydrins in high optical yield.
引用
收藏
页码:1752 / 1753
页数:2
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