ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION OF SOME ALDEHYDES BY CHIRAL TITANIUM SCHIFFS BASE COMPLEXES

被引：117

作者：

HAYASHI, M ^{[1
]}

MIYAMOTO, Y ^{[1
]}

INOUE, T ^{[1
]}

OGUNI, N ^{[1
]}

机构：

[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001752

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes formed between titanium tetraalkoxide and chiral Schiff's bases make excellent catalysts for enantioselective trimethylsilylcyanation of aldehydes to optically active cyanohydrins in high optical yield.

引用

页码：1752 / 1753

页数：2

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