NEW ROUTES FOR THE FORMATION OF TE-N BONDS - SYNTHESIS, STRUCTURE, AND PROPERTIES OF CL6TE2N2S

被引：15
|
作者：
HAAS, A
KASPROWSKI, J
PRYKA, M
机构：
来源：
CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 07期
关键词：
SELANE; BIS(SULFINYLAMIDO); REACTION WITH TECL4 AND TECL3+; TELLURIUM-NITROGEN SPECIES;
D O I：
10.1002/cber.19921250704
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Besides Cl2TeNSNSe (1), the reaction of Se(NSO)2 with TeCl4 leads to the formation of [Se2N2S]22+[TeCl5-]2 (2) and the bicyclic heterocycle Cl6Te2N2S (3). The latter is also accessible by treating Se(NSO)2 With TeCl3+AsF6-. Another product of this reaction is the well-known salt [Se2N2S]22+[AsF6-]2. Treatment of TeCl4 with Me3SiNSO in CH2Cl2 provides 3 on a preparative scale. Its structure has been determined by X-ray crystallography.
引用
收藏
页码：1537 / 1540
页数：4
相关论文
共 50 条
  • [41] Crystal structure and Raman-active lattice vibrations of magnetic topological insulators MnBi2Te4? n(Bi2Te3) (n=0, 1, ...,6) ...
    Amiraslanov, I. R.
    Aliev, Z. S.
    Askerova, P. A.
    Alizade, E. H.
    Aliyeva, Y. N.
    Abdullayev, N. A.
    Jahangirli, Z. A.
    Otrokov, M. M.
    Mamedov, N. T.
    Chulkov, E. V.
    PHYSICAL REVIEW B, 2022, 106 (18)
  • [42] Electrical Properties of Heterojunction n-MoOx/p-Cd3In2Te6
    Koziarskyi, I. P.
    Maistruk, E., V
    Koziarskyi, D. P.
    Mostovyi, A., I
    Sydor, O. M.
    Potsiluiko-Hryhoriak, H., V
    MICROSTRUCTURE AND PROPERTIES OF MICRO- AND NANOSCALE MATERIALS, FILMS, AND COATINGS (NAP 2019), 2020, 240 : 9 - 17
  • [43] CHARACTERISTICS OF AN N-SNS2-N-HG3IN2TE6 HETEROJUNCTION FORMED BY AN OPTICAL CONTACT
    ANANINA, DB
    BAKUMENKO, VL
    BONAKOV, AK
    GRUSHKA, GG
    SUSHKEVICH, TN
    FRIZEL, VV
    SOVIET PHYSICS SEMICONDUCTORS-USSR, 1980, 14 (12): : 1436 - 1438
  • [44] SYNTHESIS AND STRUCTURE OF NEW HG-TE POLYANIONS - [HG4TE12]4-, A CLUSTER CONTAINING TE-2-, TE-2(2)- AND TE-3(2)- LIGANDS AND [HG2TE5]2-, A NEW ONE-DIMENSIONAL INORGANIC POLYMER
    HAUSHALTER, RC
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (05): : 433 - 435
  • [45] FORMATION AND PROPERTIES OF HIGH-PRESSURE DEFECT PHASES WITH NACL STRUCTURE IN SYSTEM AG2TE-IN2TE3
    RANGE, KJ
    ENGERT, G
    WEISS, A
    ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1970, B 25 (10): : 1187 - &
  • [46] SYNTHESIS AND STRUCTURE OF TETRAKIS(PHENYLENETHIOUREA)TELLURIUM(II) CHLORIDE DIHYDROCHLORIDE, C2,H26N8S4CL4TE
    ROUT, GC
    SESHASAYEE, M
    ARAVAMUDAN, G
    SOWRIRAJAN, S
    POLYHEDRON, 1984, 3 (08) : 921 - 927
  • [47] Synthesis, characterisation and coordinating properties of the small ring S2Te-donor macrocycles [9]aneS2Te, [11]aneS2Te and [12]aneS2Te
    Hesford, MJ
    Levason, W
    Matthews, ML
    Orchard, SD
    Reid, G
    DALTON TRANSACTIONS, 2003, (12) : 2434 - 2442
  • [48] BIS(2-METHYLMERCAPTOBENZIMIDAZOLIUM) HEXACHLOROTELLURATE(IV) - TETRAHYDROFURAN (1/2) C24H34CL6N4O2S2TE
    HINRICHS, W
    MANDAK, D
    KLAR, G
    CRYSTAL STRUCTURE COMMUNICATIONS, 1982, 11 (01): : 309 - 314
  • [49] SYNTHESIS AND CRYSTAL-STRUCTURE OF (S4N3)2SE2CL10, (S4N3)2SE2CL6, AND [(S4N3)SECL5]N
    STAMMLER, HG
    WEISS, J
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (12): : 1483 - 1487
  • [50] Synthesis and characterization of two new copper tellurites, Ba2Cu4Te4O11Cl4 and BaCu2Te2O6Cl2, in supercritical H2O
    Feger, CR
    Kolis, JW
    INORGANIC CHEMISTRY, 1998, 37 (16) : 4046 - 4051
12345