NEW ROUTES FOR THE FORMATION OF TE-N BONDS - SYNTHESIS, STRUCTURE, AND PROPERTIES OF CL6TE2N2S

被引：15
|
作者：
HAAS, A
KASPROWSKI, J
PRYKA, M
机构：
来源：
CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 07期
关键词：
SELANE; BIS(SULFINYLAMIDO); REACTION WITH TECL4 AND TECL3+; TELLURIUM-NITROGEN SPECIES;
D O I：
10.1002/cber.19921250704
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Besides Cl2TeNSNSe (1), the reaction of Se(NSO)2 with TeCl4 leads to the formation of [Se2N2S]22+[TeCl5-]2 (2) and the bicyclic heterocycle Cl6Te2N2S (3). The latter is also accessible by treating Se(NSO)2 With TeCl3+AsF6-. Another product of this reaction is the well-known salt [Se2N2S]22+[AsF6-]2. Treatment of TeCl4 with Me3SiNSO in CH2Cl2 provides 3 on a preparative scale. Its structure has been determined by X-ray crystallography.
引用
收藏
页码：1537 / 1540
页数：4
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