OSMIUM LIII EDGE EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDIES ON THE OSMIUM(VIII) OXIDE FLUORIDES, OSO3F2, K[OSO3F3] AND CS2[OSO4F2]

被引：8
|
作者：
BREWER, SA
BRISDON, AK
HOLLOWAY, JH
HOPE, EG
LEVASON, W
OGDEN, JS
SAAD, AK
机构：
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND
[2] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 01期
关键词：
D O I：
10.1016/S0022-1139(00)82188-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Osmium L(III) edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO3F2, d(Os = O) = 1.70 angstrom and d(Os = F) = 1.89 and 2.09 angstrom, for K[OsO3F3], d(Os = O) = 1.70 angstrom and d(Os = F) = 1.92 angstrom and, for Cs2[OsO4F2], d(Os = 0) = 1.70 angstrom and d(Os-F) = 2.05 angstrom (bond lengths accurate to +/- 0.02 angstrom).
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页码：13 / 17
页数：5
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