OSMIUM LIII EDGE EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDIES ON THE OSMIUM(VIII) OXIDE FLUORIDES, OSO3F2, K[OSO3F3] AND CS2[OSO4F2]

被引：8

作者：

BREWER, SA

BRISDON, AK

HOLLOWAY, JH

HOPE, EG

LEVASON, W

OGDEN, JS

SAAD, AK

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82188-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Osmium L(III) edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO3F2, d(Os = O) = 1.70 angstrom and d(Os = F) = 1.89 and 2.09 angstrom, for K[OsO3F3], d(Os = O) = 1.70 angstrom and d(Os = F) = 1.92 angstrom and, for Cs2[OsO4F2], d(Os = 0) = 1.70 angstrom and d(Os-F) = 2.05 angstrom (bond lengths accurate to +/- 0.02 angstrom).

引用

页码：13 / 17

页数：5

共 50 条

[21] X-RAY SINGLE-CRYSTAL STRUCTURE DETERMINATIONS OF THE POTASSIUM COPPER(II) FLUORIDES K2CUF4 AND K3CU2F7
HERDTWECK, E
BABEL, D
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 474 (03): : 113 - 122
[22] STRUCTURES OF ALUMINA-SUPPORTED OSMIUM CLUSTERS (HOS3(CO)10(OAL)) AND COMPLEXES (OSII(CO)N=2OR3(OAL)3) DETERMINED BY EXTENDED X-RAY ABSORPTION FINE-STRUCTURE SPECTROSCOPY
DUIVENVOORDEN, FBM
KONINGSBERGER, DC
UH, YS
GATES, BC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (20) : 6254 - 6262
[23] Extended X-ray absorption fine-structure (EXAFS) of a complex oxide structure:: a full multiple scattering analysis of the Au L3-edge EXAFS of Au2O3
Weiher, N
Willneff, EA
Figulla-Kroschel, C
Jansen, M
Schroeder, SLM
SOLID STATE COMMUNICATIONS, 2003, 125 (06) : 317 - 322
[24] Lewis acid behavior of ReO2F3:: Synthesis of (ReO2F3)∞, ReO2F4-, Re2O4F7-, Re3O6F10- and ReO2F3(CH3CN) and study by NMR spectroscopy, Raman spectroscopy, and density functional theory calculations;: and X-ray structures of [Li][ReO2F4], [K][Re2O4F7], [K][Re2O4F7]•2ReO2F3, [Cs][Re3O6F10], and ReO3F(CH3CN)2•CH3CN
Casteel, WJ
Dixon, DA
LeBlond, N
Lock, PE
Mercier, HPA
Schrobilgen, GJ
INORGANIC CHEMISTRY, 1999, 38 (10) : 2340 - 2358
[25] [XeOXeOXe]2+, the Missing Oxide of Xenon(II); Synthesis, Raman Spectrum, and X-ray Crystal Structure of [XeOXeOXe][μ-F(ReO2F3)2]2
Ivanova, Maria V.
Mercier, Helene P. A.
Schrobilgen, Gary J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (41) : 13398 - 13413
[26] EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDIES OF BIMETALLIC CU-NI/GAMMA-AL2O3 CATALYSTS
SANKAR, G
VASUDEVAN, S
RAO, CNR
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (21): : 5325 - 5328
[27] X-RAY ABSORPTION FINE-STRUCTURE STUDIES OF FE-DOPED BA2YCU3OY
OYANAGI, H
OBARA, H
YAMAGUCHI, H
MURATA, K
IHARA, H
MATSUSHITA, T
TOKUMOTO, M
NISHIHARA, Y
KIMURA, Y
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1989, 58 (06) : 2140 - 2146
[28] EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE STUDIES OF TRANSITION-METAL PERIODATE AND TELLURATE COMPLEXES - CRYSTAL-STRUCTURE OF RB2NA4[OSO2(H2TEO6)(2)]CENTER-DOT-16H2O
LEVASON, W
OLDROYD, RD
WEBSTER, M
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (20): : 2983 - 2988
[29] EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDIES ON THE STRUCTURE CHANGE OF THE AL2O3-ATTACHED [CO-2]4 CATALYST DURING A CO OXIDATION REACTION
ASAKURA, K
IWASAWA, Y
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (10): : 4213 - 4218
[30] Synthesis and structure of Ba(2)InO(3)X (X=F,Cl,Br) and Ba2ScO3F; Oxide/halide ordering in K2NiF4-type structures
Needs, RL
Weller, MT
Scheler, U
Harris, RK
JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (07) : 1219 - 1224

← 1 2 3 4 5 →