OSMIUM LIII EDGE EXTENDED X-RAY ABSORPTION FINE-STRUCTURE STUDIES ON THE OSMIUM(VIII) OXIDE FLUORIDES, OSO3F2, K[OSO3F3] AND CS2[OSO4F2]

被引：8

作者：

BREWER, SA

BRISDON, AK

HOLLOWAY, JH

HOPE, EG

LEVASON, W

OGDEN, JS

SAAD, AK

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 60卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)82188-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Osmium L(III) edge extended X-ray absorption fine-structure data have been obtained for the title compounds and refined to give, for OsO3F2, d(Os = O) = 1.70 angstrom and d(Os = F) = 1.89 and 2.09 angstrom, for K[OsO3F3], d(Os = O) = 1.70 angstrom and d(Os = F) = 1.92 angstrom and, for Cs2[OsO4F2], d(Os = 0) = 1.70 angstrom and d(Os-F) = 2.05 angstrom (bond lengths accurate to +/- 0.02 angstrom).

引用

页码：13 / 17

页数：5

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