The photoexcited neutral states of the Sn donors in Ga1-xAlxAs alloys are studied both experimentally and theoretically. Two types of donor states are evidenced: a deep strongly localized one, D0, as well as a delocalized effective-mass state d0. Both belong to the principal donor Sn(Ga), as confirmed by EPR measurements on Sn-119-enriched samples. The D0 state is consistently modeled as the A1(ab) antibonding donor state. Theory predicts the coexistence of both states D0, d0 in an intermediate alloying range. This level scheme also explains the results of the Si and Te donor reported previously.