PECULIARITIES OF THERMOCHEMISTRY OF LITHIUM PERCHLORATE SOLUTIONS IN MIXED METHANOL-DIOXANE SOLVENT WITH LOW CONCENTRATIONS

被引：0
|
作者：
MASHKOV, MY
VELIKOV, AA
机构：
来源：
SIBIRSKII KHIMICHESKII ZHURNAL | 1992年 / 01期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dilution enthalpies of lithium perchlorate in mixed methanol-dioxane solvent at 293 K in a wide range of solvent compositions have been measured. A good agreement between characteristic sections of concentration functions of conductances and total enthalpies of dilution was shown. An extremum of concentration dependences on intermediate enthalpies of dilution which affects the magnitude of the limiting slope was detected. Thus it is necessary for such systems to use data with possibly low concentrations for correct determination of total enthalpy of dilution.
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页码：18 / 20
页数：3
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