PECULIARITIES OF THERMOCHEMISTRY OF LITHIUM PERCHLORATE SOLUTIONS IN MIXED METHANOL-DIOXANE SOLVENT WITH LOW CONCENTRATIONS

被引：0
|
作者：
MASHKOV, MY
VELIKOV, AA
机构：
来源：
SIBIRSKII KHIMICHESKII ZHURNAL | 1992年 / 01期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dilution enthalpies of lithium perchlorate in mixed methanol-dioxane solvent at 293 K in a wide range of solvent compositions have been measured. A good agreement between characteristic sections of concentration functions of conductances and total enthalpies of dilution was shown. An extremum of concentration dependences on intermediate enthalpies of dilution which affects the magnitude of the limiting slope was detected. Thus it is necessary for such systems to use data with possibly low concentrations for correct determination of total enthalpy of dilution.
引用
收藏
页码：18 / 20
页数：3
相关论文
共 50 条
  • [41] RESEARCH ON LOW-COST FLUORINE-FREE AQUEOUS MIXED SOLVENT LITHIUM ACETATE ELECTROLYTES
    Wu, Fan
    Jiang, Wenquan
    Luo, Man
    Wu, Yuanfang
    Zhang, Yongqiang
    He, Wenxiu
    [J]. Taiyangneng Xuebao/Acta Energiae Solaris Sinica, 2023, 44 (08): : 17 - 22
  • [42] Excess Volume of Mixing of 1:1 Electrolyte Solutions at 298.15 K in the Aquo-1,4-Dioxane Mixed-Solvent System
    Bal Raj Deshwal
    Krishan Chander Singh
    [J]. Journal of Solution Chemistry, 2005, 34 : 755 - 767
  • [43] Solubilities of isobutane in methanol plus benzene, methanol plus cyclohexane and benzene plus cyclohexane mixed solvent solutions at 298 K and 40-102 kPa
    Miyano, Y
    Hayduk, W
    [J]. FLUID PHASE EQUILIBRIA, 1997, 135 (02) : 259 - 268
  • [44] Solubilities of isobutene in methanol plus benzene, methanol plus cyclohexane and benzene plus cyclohexane mixed solvent solutions at 298 K and 27-102 kPa
    Miyano, Y
    Nakanishi, K
    [J]. FLUID PHASE EQUILIBRIA, 2003, 204 (01) : 131 - 142
  • [45] ATTENUATED TOTAL REFLECTION FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDY OF ION SOLVENT AND ION ION INTERACTIONS IN LITHIUM PERCHLORATE NITROMETHANE SOLUTIONS
    FAGUY, PW
    FAWCETT, WR
    PATRICK, DL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (18): : 2961 - 2965
  • [46] Enthalpy of mixing of 1:1 electrolytic solutions at varying ionic strength at 298.15 K in water+1,4-dioxane mixed solvent system
    Deshwal, BR
    Singh, KC
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2003, 42 (03): : 467 - 472
  • [47] Preferential solvation and ionic association in lithium and silver trifluomethanesulfonate solutions in acrylonitrile/dimethylsulfoxide mixed solvent -: A Raman spectroscopic study
    Alía, JM
    Edwards, HGM
    Lawson, EE
    [J]. VIBRATIONAL SPECTROSCOPY, 2004, 34 (02) : 187 - 197
  • [48] A preliminary study for fiber spinning of mixed solutions of polyrotaxane and cellulose in a dimethylacetamide/lithium chloride (DMAc/LiCl) solvent system
    Araki, Jun
    Kataoka, Toshiyuki
    Katsuyama, Naoya
    Teramoto, Akira
    Ito, Kohzo
    Abe, Koji
    [J]. POLYMER, 2006, 47 (25) : 8241 - 8246
  • [49] Studies on solute-solvent interaction of different concentrated solutions of 1-carboxamido pyrazoline in 70% dioxane-water and methanol-water by viscosity measurement
    Raghuwanshi, PB
    Deshmukh, AY
    Doshi, AG
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2003, 15 (03) : 1535 - 1538
  • [50] Electrical conductivity of solutions of lithium bis(fluorosulfonyl)imide in mixed organic solvents and multi-objective solvent optimization for lithium-ion batteries
    Neuhaus, Johannes
    Forte, Esther
    von Harbou, Erik
    Hasse, Hans
    [J]. JOURNAL OF POWER SOURCES, 2018, 398 : 215 - 223
12345