Solvation of lithium chloride in aqueous and mixed solutions of an aprotic solvent

被引：2
|
作者：
Zabolotskii, V. I. [1 ]
Demin, A. V. [1 ]
Demina, O. A. [1 ]
机构：
[1] Kuban State Univ, Krasnodar 350040, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2013年 / 87卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
solvation; lithium chloride; mixed solutions; aprotic solvent; ELECTRODIALYSIS; WATER; ION;
D O I：
10.1134/S0036024413020155
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The dynamic hydration and solvation numbers of lithium chloride are estimated on the basis of experimental data on the limiting electrodialysis concentration of an electrolyte from aqueous and aqueousorganic solutions containing aprotic solvent N,N-dimethylacetamide. It is established that the dependence of the hydration numbers of the salt on the volume fraction of the aprotic solvent is of an extreme character, and its solvation number on N,N-dimethylacetamide does not depend on the composition of the mixed solution.
引用
收藏
页码：194 / 198
页数：5
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