{N, N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl] methylamine-kappa(2) P, P'}bis(eta(5)-cyclopentadienyl) titanium(II)

被引：1
|
作者：
Haehnel, Martin [1 ]
Hansen, Sven [1 ]
Spannenberg, Anke [1 ]
Beweries, Torsten [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813014244
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ti(C5H5)(2)(C9H11F12NO4P2)], is a fourmembered titanacycle obtained from the reaction of Cp2Ti(eta(2) Me3SiC2SiMe3) and CH3N[P(OCH2CF3)(2)](2) {N, N-bis[ bis( trifluoroethoxy) phosphanyl] methylamine, tfepma}. The Ti-II atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.
引用
收藏
页码：M346 / +
页数：8
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