{N, N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl] methylamine-kappa(2) P, P'}bis(eta(5)-cyclopentadienyl) titanium(II)

被引：1

作者：

Haehnel, Martin ^{[1
]}

Hansen, Sven ^{[1
]}

Spannenberg, Anke ^{[1
]}

Beweries, Torsten ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813014244

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ti(C5H5)(2)(C9H11F12NO4P2)], is a fourmembered titanacycle obtained from the reaction of Cp2Ti(eta(2) Me3SiC2SiMe3) and CH3N[P(OCH2CF3)(2)](2) {N, N-bis[ bis( trifluoroethoxy) phosphanyl] methylamine, tfepma}. The Ti-II atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.

引用

页码：M346 / +

页数：8

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