INTERACTION OF TETRABUTOXYTITANIUM WITH COMPONENTS OF THE REACTION SYSTEM OF PROCESSES OF ESTERIFICATION AND TRANSESTERIFICATION

被引：0
|
作者：
BULAI, AK
SLONIM, IY
BARSHTEIN, RS
SOROKINA, IA
GORBUNOVA, VG
机构：
来源：
KINETICS AND CATALYSIS | 1990年 / 31卷 / 03期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reaction mixtures formed in the interaction of the catalyst Ti(OBu)4 with the starting materials of the reactions of esterification and transesterification were investigated by the NMR method. It was shown that even at room temperature the catalyst interacts with alcohols, acids, glycols, and esters. In the reaction of transesterification, the alcohol residue bonded to the Ti atom is more active than the free glycol, while in the esterification reaction, the amphoteric titanium base is more active than the alcohol.
引用
收藏
页码：522 / 528
页数：7
相关论文
共 50 条
  • [31] Reaction kinetics with catalyst deactivation in simultaneous esterification and transesterification of acid oils to biodiesel (FAME) over a mesoporous sulphonated carbon catalyst
    Konwar, Lakhya Jyoti
    Warna, Johan
    Maki-Arvela, Paivi
    Kumar, Narendra
    Mikkola, Jyri-Pekka
    FUEL, 2016, 166 : 1 - 11
  • [32] Esterification of hydrophobic substrates by lipase in the cyclodextrin induced emulsion reaction system
    Shin, HD
    Kim, JH
    Kim, TK
    Kim, SH
    Lee, YH
    ENZYME AND MICROBIAL TECHNOLOGY, 2002, 30 (07) : 835 - 842
  • [33] Improvement of the enzymatic synthesis of ethyl valerate by esterification reaction in a solvent system
    Corradini, Maria Carolina C.
    Costa, Breno M.
    Bressani, Ana Paula P.
    Garcia, Karen C. A.
    Pereira, Ernandes B.
    Mendes, Adriano A.
    PREPARATIVE BIOCHEMISTRY & BIOTECHNOLOGY, 2017, 47 (01): : 100 - 109
  • [34] PROCESSES OF INTERACTION OF PETROLEUM-PRODUCTS WITH CONCRETE AND WITH CONCRETE COMPONENTS
    VASILEV, NM
    COLLOID JOURNAL OF THE USSR, 1985, 47 (03): : 375 - 380
  • [35] PRIMARY PROCESSES IN REACTION OF INTERACTION OF CHLOROPHYLL WITH METHYL VIOLOGEN
    CHIBISOV, AK
    KARYAKIN, AV
    YEVSTIGN.VB
    BIOPHYSICS-USSR, 1966, 11 (06): : 1125 - &
  • [36] The "spectrum dip": Dynamic interaction of system components
    Scavuzzo, Rudolph J.
    Hill, George D.
    Saxe, Peter
    PROCEEDINGS OF THE ASME PRESSURE VESSELS AND PIPING CONFERENCE 2007, VOL 8: SEISMIC ENGINEERING, 2007, : 81 - 96
  • [37] Temporal interaction contracts for components in a distributed system
    Tilak, Omkar J.
    Raje, Rajeev R.
    11TH IEEE INTERNATIONAL ENTERPRISE DISTRIBUTED OBJECT COMPUTING CONFERENCE, PROCEEDINGS, 2007, : 339 - 349
  • [38] The "Spectrum Dip": Dynamic Interaction of System Components
    Scavuzzo, Rudolph J.
    Hill, George D.
    Saxe, Peter
    JOURNAL OF PRESSURE VESSEL TECHNOLOGY-TRANSACTIONS OF THE ASME, 2015, 137 (04):
  • [39] APPROACHES TO PREDICTING THE INTERACTION OF COMPONENTS IN PRINTING SYSTEM
    Orlova, E. Yu
    Chernaya, I., V
    Sultanova, Yu M.
    Varepo, L. G.
    Trapeznikova, O., V
    Rovenskikh, A. A.
    PROCEEDINGS OF THE TULA STATES UNIVERSITY-SCIENCES OF EARTH, 2021, 3 : 358 - 365
  • [40] Optimal Operation of Batch Reactive Distillation Process Involving Esterification Reaction System
    Edreder, Elmahboub
    Mujtaba, Iqbal M.
    Emtir, Mansour
    ICHEAP12: 12TH INTERNATIONAL CONFERENCE ON CHEMICAL & PROCESS ENGINEERING, 2015, 43 : 1387 - 1392
12345