INTERACTION OF TETRABUTOXYTITANIUM WITH COMPONENTS OF THE REACTION SYSTEM OF PROCESSES OF ESTERIFICATION AND TRANSESTERIFICATION

被引:0
|
作者
BULAI, AK
SLONIM, IY
BARSHTEIN, RS
SOROKINA, IA
GORBUNOVA, VG
机构
关键词
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction mixtures formed in the interaction of the catalyst Ti(OBu)4 with the starting materials of the reactions of esterification and transesterification were investigated by the NMR method. It was shown that even at room temperature the catalyst interacts with alcohols, acids, glycols, and esters. In the reaction of transesterification, the alcohol residue bonded to the Ti atom is more active than the free glycol, while in the esterification reaction, the amphoteric titanium base is more active than the alcohol.
引用
收藏
页码:522 / 528
页数:7
相关论文
共 50 条
  • [21] THE ANALYSIS OF THE STRUCTURE OF THE REACTION-RECTIFICATION SYSTEM FOR THE ESTERIFICATION PROCESS
    KUZNIEWSKALACH, I
    INZYNIERIA CHEMICZNA I PROCESOWA, 1994, 15 (02): : 299 - 315
  • [22] Synthesis of phosphatidylcholine with defined fatty acid in the sn-1 position by lipase-catalyzed esterification and transesterification reaction
    Adlercreutz, D
    Budde, H
    Wehtje, E
    BIOTECHNOLOGY AND BIOENGINEERING, 2002, 78 (04) : 403 - 411
  • [23] Characterization and Efficiency of ZnAl2O4 Spinel Synthesized by Combustion Reaction on the Esterification and Transesterification of Soybean Oil
    Feitosa, Alex Cavalcanti
    Leal, Elvia
    Barbosa, Daniela Costa
    Plentz Meneghetti, Simoni Margareti
    Goldsmith Aliaga Kiminami, Ruth Herta
    Figueiredo de Melo Costa, Ana Cristina
    ADVANCED POWDER TECHNOLOGY VIII, PTS 1 AND 2, 2012, 727-728 : 1919 - +
  • [24] Interaction among lignocellulosic biomass components in thermochemical processes
    Ricciulli, Miriam O.
    Arce, Gretta L. A. F.
    Vieira, Eliana C.
    Avila, Ivonete
    BIOMASS & BIOENERGY, 2024, 182
  • [25] Interaction between visual and motor components in imagery processes
    Hishitani, S
    INTERNATIONAL JOURNAL OF PSYCHOLOGY, 1996, 31 (3-4) : 2173 - 2173
  • [26] REACTION OF DIBUTYLTIN DILAURATE WITH COMPONENTS OF A POLYTRANSESTERIFICATION REACTION SYSTEM
    BULAI, AK
    SLONIM, IY
    ARSHAVA, BM
    BARSHTEIN, RS
    GORBUNOVA, VG
    KINETICS AND CATALYSIS, 1991, 32 (03) : 541 - 549
  • [27] Phase equilibrium of transesterification reaction system between soybean oil and methanol
    Zhang J.
    Liu H.
    Huagong Xuebao/CIESC Journal, 2022, 73 (05): : 1920 - 1929
  • [28] INTERACTION OF COMPONENTS OF LACTOSE SYNTHETASE SYSTEM
    OSBORNE, JC
    STEINER, RF
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 1974, 165 (02) : 615 - 627
  • [29] Polyurethane adhesive system from castor oil modified by a transesterification reaction
    Valero, Manuel F.
    Gonzalez, Adriana
    JOURNAL OF ELASTOMERS AND PLASTICS, 2012, 44 (05): : 433 - 442
  • [30] Synthesis, Characterization and Catalytic Performance of Mixed Nanoferrites Submitted to Transesterification and Esterification Reaction Using Methyl and Ethyl Route for Biodiesel Production
    Dantas, Joelda
    Leal, Elvia
    Mapossa, Antonio Benjamim
    Silva, Adriano Sant'Ana
    Figueiredo de Melo Costa, Ana Cristina
    MATERIA-RIO DE JANEIRO, 2016, 21 (04): : 1080 - 1093