PHASE-TRANSFER CATALYSIS WITHOUT SOLVENT - SELECTIVE MONOALKYLATION OR DIALKYLATION OF MALONONITRILE

被引：41

作者：

DIEZBARRA, E

DELAHOZ, A

MORENO, A

SANCHEZVERDU, P

机构：

[1] Facultad de Química, Universidad de Castilla-La Manche

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 10期

关键词：

D O I：

10.1039/p19910002589

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Monoalkyl and symmetrical or unsymmetrical dialkylmalononitriles have been prepared selectively by phase transfer catalysis in the absence of solvent. Exclusive formation of a particular compound is achieved in all cases except for benzylmalononitrile 2f (79%) and prop-2-ynylmalononitrile 2g (62%).

引用

页码：2589 / 2592

页数：4

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