PHASE-TRANSFER CATALYSIS WITHOUT SOLVENT - SELECTIVE MONOALKYLATION OR DIALKYLATION OF MALONONITRILE

被引：41
|
作者：
DIEZBARRA, E
DELAHOZ, A
MORENO, A
SANCHEZVERDU, P
机构：
[1] Facultad de Química, Universidad de Castilla-La Manche
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 10期
关键词：
D O I：
10.1039/p19910002589
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Monoalkyl and symmetrical or unsymmetrical dialkylmalononitriles have been prepared selectively by phase transfer catalysis in the absence of solvent. Exclusive formation of a particular compound is achieved in all cases except for benzylmalononitrile 2f (79%) and prop-2-ynylmalononitrile 2g (62%).
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页码：2589 / 2592
页数：4
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