PHASE-TRANSITIONS IN [FE3O(OOCCD3)6(C5H5N)3](C5H5N) - EVIDENCE FROM INCOHERENT NEUTRON-SCATTERING

被引：15
|
作者：
CANNON, RD
JAYASOORIYA, UA
ARAPKOSKE, SK
WHITE, RP
WILLIAMS, JH
机构：
[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND
[2] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 11期
关键词：
D O I：
10.1021/ja00011a017
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
For [Fe3O(OOCCD3)6(C5H5N)3](C5H5N) elastic and quasielastic incoherent neutron scattering measurements are shown to give information on structural reorganization and molecular motions which correlates well with data derived from heat capacity measurements. Phase changes are identified, and clear evidence is obtained for a large increase in molecular motion between 200 and 300 K.
引用
收藏
页码：4158 / 4160
页数：3
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