INFLUENCING THE AGGREGATION OF MANGANESE COMPLEXES BY DIFFERENT BASES - FORMATION OF [MN(O2CCF3)2(PY)4] AND [MN3(O2CCF3)6(BENZ)6]

被引：35
|
作者：
HUBNER, K [1 ]
ROESKY, HW [1 ]
NOLTEMEYER, M [1 ]
BOHRA, R [1 ]
机构：
[1] UNIV GOTTINGEN, INST ANORGAN CHEM, TAMMANNSTR 4, W-3400 GOTTINGEN, GERMANY
来源：
CHEMISCHE BERICHTE-RECUEIL | 1991年 / 124卷 / 03期
关键词：
MANGANESE COMPLEXES; AGGREGATION;
D O I：
10.1002/cber.19911240316
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Manganese powder reacts quantitatively with trifluoroacetic acid to yield Mn(O2CCF3)2 (1). The aggregation of 1 is directed by different N-containing bases. Pyridine (py) forms the mononuclear complex [Mn(O2CCF3)2(py)4] (2), while benzonitrile (benz) yields the trinuclear complex [Mn3(O2CCF3)6(benz)6] (3). The X-ray structures of 2 and 3 are described.
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页码：515 / 517
页数：3
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