THEORETICAL-STUDY OF FREE-RADICAL RING-OPENING POLYMERIZATION OF 2-(O-CHLOROPHENYL)-4-METHYLENE-1,3-DIOXOLANE - A MOLECULAR AND QUANTUM-MECHANICS APPROACH

被引：4

作者：

MORARIU, S

SURPATEANU, G

SIMIONESCU, BC

机构：

[1] GHE ASACHI TECH UNIV,DEPT MACROMOLEC,R-6600 IASI,ROMANIA

[2] PETRU PONI INST MACROMOLEC CHEM,R-6600 IASI,ROMANIA

[3] AL I CUZA UNIV,DEPT ORGAN CHEM,R-6600 IASI,ROMANIA

来源：

MACROMOLECULAR THEORY AND SIMULATIONS | 1994年 / 3卷 / 02期

关键词：

D O I：

10.1002/mats.1994.040030219

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The methylene derivatives of 1,3-dioxolane were proved to yield homo- and binary or ternary copolymers via free-radical polymerization, depending on initiation type and reaction conditions. While different authors reported experimental data on these compounds, no explanation of such polymerization behaviour was provided. The present paper is aimed to propose, through molecular mechanics and quantum mechanics approaches, a valid explanation of the already published experimental results.

引用

页码：523 / 531

页数：9

共 29 条

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ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 236 - POLY

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