MG-PROMOTED REDUCTIVE CROSS-COUPLING OF CARBONYL-COMPOUNDS WITH TRIMETHYLSILYL CHLORIDE

被引：11

作者：

ISHINO, Y ^{[1
]}

MAEKAWA, H ^{[1
]}

TAKEUCHI, H ^{[1
]}

SUKATA, K ^{[1
]}

NISHIGUCHI, I ^{[1
]}

机构：

[1] ORIENT CHEM IND LTD, NEYAGAWA, OSAKA 572, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 09期

关键词：

D O I：

10.1246/cl.1995.829

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mg-promoted cross-coupling of aromatic carbonyl compounds with trimethylsilyl chloride (TMSCl) in DMF at room temperature brought about reductive carbon-silicon bond formation to give the corresponding alpha-trimethylsilylalkyl trimethylsilyl ethers selectively in good yields. The reaction may be initiated through electron transfer from Mg metal to the carbonyl compounds.

引用

页码：829 / 830

页数：2

共 50 条

[41] REDUCTIVE AMINATION OF CARBONYL-COMPOUNDS IN THE PRESENCE OF COBALT AND RHODIUM COMPLEXES
KLYUEV, MV
KHIDEKEL, ML
TRANSITION METAL CHEMISTRY, 1980, 5 (03) : 134 - 139
[42] A CONVENIENT AND SELECTIVE METHOD FOR REDUCTIVE DEUTERIATION OF ARYL CARBONYL-COMPOUNDS
OFOSUASANTE, K
STOCK, LM
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (13): : 2938 - 2939
[43] REDUCTIVE COUPLING OF ALLYLIC ACETATES WITH CARBONYL-COMPOUNDS BY USING PD(O)-SMI2 SYSTEM
TABUCHI, T
INANAGA, J
YAMAGUCHI, M
TETRAHEDRON LETTERS, 1986, 27 (10) : 1195 - 1196
[44] BIS(TRIMETHYLSILYL) SULFATE-SILICA CATALYZED THIOACETALISATION OF CARBONYL-COMPOUNDS
PATNEY, HK
TETRAHEDRON LETTERS, 1993, 34 (44) : 7127 - 7128
[45] SELECTIVE FORMATION OF ALKYL AZIDES USING TRIMETHYLSILYL AZIDE AND CARBONYL-COMPOUNDS
NISHIYAMA, K
YAMAGUCHI, T
SYNTHESIS-STUTTGART, 1988, (02): : 106 - 108
[46] Trimethylsilyl chloride-accelerated reduction and pinacol coupling of carbonyl compounds by means of samarium diiodide
Honda, T
Katoh, M
CHEMICAL COMMUNICATIONS, 1997, (04) : 369 - 370
[47] BIS(TRIMETHYLSILYL)SULFIDE BASED THIONATION OF CARBONYL-COMPOUNDS - SYNTHESIS OF THIOKETONES
DEGL'INNOCENTI, A
CAPPERUCCI, A
MORDINI, A
REGINATO, G
RICCI, A
CERRETA, F
TETRAHEDRON LETTERS, 1993, 34 (05) : 873 - 876
[48] LEAD-PROMOTED ALLYLATION OF CARBONYL-COMPOUNDS WITH ALLYL BROMIDE
TANAKA, H
YAMASHITA, S
HAMATANI, T
IKEMOTO, Y
TORII, S
CHEMISTRY LETTERS, 1986, (09) : 1611 - 1614
[49] CONVERSION OF ACETALS AND KETALS TO CARBONYL-COMPOUNDS PROMOTED BY TITANIUM TETRACHLORIDE
BALME, G
GORE, J
JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (19): : 3336 - 3338
[50] ALKYLALUMINUM CHLORIDE INDUCED CYCLIZATION OF UNSATURATED CARBONYL-COMPOUNDS
KARRAS, M
SNIDER, BB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (27) : 7951 - 7953

← 1 2 3 4 5 →