MG-PROMOTED REDUCTIVE CROSS-COUPLING OF CARBONYL-COMPOUNDS WITH TRIMETHYLSILYL CHLORIDE

被引：11

作者：

ISHINO, Y ^{[1
]}

MAEKAWA, H ^{[1
]}

TAKEUCHI, H ^{[1
]}

SUKATA, K ^{[1
]}

NISHIGUCHI, I ^{[1
]}

机构：

[1] ORIENT CHEM IND LTD, NEYAGAWA, OSAKA 572, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 09期

关键词：

D O I：

10.1246/cl.1995.829

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mg-promoted cross-coupling of aromatic carbonyl compounds with trimethylsilyl chloride (TMSCl) in DMF at room temperature brought about reductive carbon-silicon bond formation to give the corresponding alpha-trimethylsilylalkyl trimethylsilyl ethers selectively in good yields. The reaction may be initiated through electron transfer from Mg metal to the carbonyl compounds.

引用

页码：829 / 830

页数：2

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