PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .18. SYNTHESIS AND STUDY OF VANADIUM-CONTAINING MONOMERS

被引：3
|
作者：
POMOGAILO, AD
GOLUBEVA, ND
KITAIGORODSKII, AN
机构：
[1] N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR,Chernogolovka Branch
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 02期
关键词：
D O I：
10.1007/BF00965442
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Esters of orthovanadic acid with unsaturated groups were synthesized for the first time by transesterification. Vanadium-containing monomers with the monomethyl methacrylate ester of ethylene glycol (MEG) and dimethylvinylethynylcarbinol proved the most stable. All three isopropoxy groups are consecutively replaced in OV(O-i-C3H7)3 by MEG alkoxy groups. Three pure vanadium-containing monomers were obtained capable of polymerization.
引用
收藏
页码：418 / 420
页数：3
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