Synthesis and reactivity of metal-containing monomers - 49. Synthesis and structure of low-valence transition metal acrylates and their polymers

被引:1
|
作者
Dzhardimalieva, GI [1 ]
Ivleva, IN [1 ]
Shul'ga, YM [1 ]
Frolov, EN [1 ]
Pomogailo, AD [1 ]
机构
[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Russia
关键词
metal acrylates; metal in lowest oxidation state; metal polyacrylates; synthesis; structure;
D O I
10.1007/BF02503481
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The methods for synthesis of Cu1+, Fe2+, Cr2+, and V3+ acrylates were elaborated. The compounds obtained were characterized by elemental analyses, data of IR, X-ray photoelectron, and Mossbauer spectroscopy, magnetochemistry, and mass spectrometry. Polymeric products were obtained by liquid-phase radical polymerization of metal acrylates. Changes in the electronic state of the ions and their nearest ligand environment during polymerization were observed.
引用
收藏
页码:1113 / 1117
页数:5
相关论文
共 50 条
  • [1] Synthesis and reactivity of metal-containing monomers 49. Synthesis and structure of low-valence transition metal acrylates and their polymers
    G. I. Dzhardimalieva
    I. N. Ivleva
    Yu. M. Shul'ga
    E. N. Frolov
    A. D. Pomogailo
    Russian Chemical Bulletin, 1998, 47 : 1113 - 1117
  • [2] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .7. SYNTHESIS AND STUDY OF TRANSITION-METAL ACRYLATES
    DZHARDIMALIEVA, GI
    POMOGAILO, AD
    PONOMAREV, VI
    ATOVMYAN, LO
    SHULGA, YM
    STARIKOV, AG
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (07): : 1346 - 1351
  • [3] SYNTHESIS AND REACTIVITY OF METAL-CONTAINING MONOMERS .20. PHOTOCHEMICAL STRUCTURIZATION OF GELATIN MIXTURES WITH THE PARTICIPATION OF TRANSITION-METAL ACRYLATES
    BOTSMAN, AV
    FEDOROVA, LN
    VASILCHENKO, AI
    DZHARDIMALIEVA, GI
    POMOGAILO, AD
    BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE, 1992, 41 (03): : 454 - 458
  • [4] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .19. COPOLYMERIZATION OF TRANSITION-METAL ACRYLATES
    DZHARDIMALIEVA, GI
    POMOGAILO, AD
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (02): : 297 - 302
  • [5] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .8. POLYMERIZATION OF TRANSITION-METAL ACRYLATES
    DZHARDIMALIEVA, GI
    POMOGAILO, AD
    DAVTYAN, SP
    PONOMAREV, VI
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (07): : 1352 - 1357
  • [6] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
    Dzhardimalieva, G. I.
    Semenov, S. A.
    Knerelman, E. I.
    Davydova, G. I.
    Kydralieva, K. A.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2016, 26 (06) : 1441 - 1451
  • [7] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
    G. I. Dzhardimalieva
    S. A. Semenov
    E. I. Knerelman
    G. I. Davydova
    K. A. Kydralieva
    Journal of Inorganic and Organometallic Polymers and Materials, 2016, 26 : 1441 - 1451
  • [8] Preparation and reactivity of metal-containing monomers .44. Synthesis and structure of vinylporphyrins and their metal complexes
    Kitsenko, NA
    Ishkov, YV
    Voloshanovskii, IS
    Aliev, ZG
    Pomogailo, AD
    RUSSIAN CHEMICAL BULLETIN, 1995, 44 (09) : 1758 - 1763
  • [9] Synthesis and reactivity of metal-containing monomers52. Synthesis and structure of TiIV-containing optically active monomers
    E. I. Klabunovskii
    E. I. Karpeiskaya
    G. I. Dzhardimalieva
    N. D. Golubeva
    A. D. Pomogailo
    Russian Chemical Bulletin, 1999, 48 : 1717 - 1721
  • [10] Synthesis and reactivity of metal-containing monomers 52.: Synthesis and structure of TiIV-containing optically active monomers
    Klabunovskii, EI
    Karpeiskaya, EI
    Gzhardimalieva, GI
    Golubeva, ND
    Pomogailo, AD
    RUSSIAN CHEMICAL BULLETIN, 1999, 48 (09) : 1717 - 1721