Synthesis and reactivity of metal-containing monomers - 49. Synthesis and structure of low-valence transition metal acrylates and their polymers

被引：1
|
作者：
Dzhardimalieva, GI [1 ]
Ivleva, IN [1 ]
Shul'ga, YM [1 ]
Frolov, EN [1 ]
Pomogailo, AD [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 1998年 / 47卷 / 06期
关键词：
metal acrylates; metal in lowest oxidation state; metal polyacrylates; synthesis; structure;
D O I：
10.1007/BF02503481
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The methods for synthesis of Cu1+, Fe2+, Cr2+, and V3+ acrylates were elaborated. The compounds obtained were characterized by elemental analyses, data of IR, X-ray photoelectron, and Mossbauer spectroscopy, magnetochemistry, and mass spectrometry. Polymeric products were obtained by liquid-phase radical polymerization of metal acrylates. Changes in the electronic state of the ions and their nearest ligand environment during polymerization were observed.
引用
收藏
页码：1113 / 1117
页数：5
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