PALLADIUM-COMPLEX-CATALYZED DECARBOXYLATION CARBONYLATION OF ALLYL DIETHYLCARBAMATES

被引：0
|
作者：
MIYAZAWA, M [1 ]
WANG, SZ [1 ]
TAKEDA, H [1 ]
YAMAMOTO, K [1 ]
机构：
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN
来源：
SYNLETT | 1992年 / 04期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diethylcarbamic acid allylic esters 1 undergo decarboxylation-carbonylation to give the corresponding beta,gamma-unsaturated amides 2 under rather forcing conditions [CO (50-80 atm) at 100-degrees-C] in the presence of a palladium(0)-triphenylphosphine complex as catalyst.
引用
收藏
页码：323 / 324
页数：2
相关论文
共 50 条
  • [41] Palladium catalyzed decarboxylation reactions of nonsymmetrical pentadienyl dienoates
    Vummalaneni, Rupa M.
    Sayed, Sommayah M.
    Nagy, Emma E.
    Hyatt, I. F. Dempsey
    Gettys, Kristen E.
    Croatt, Mitchell P.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [42] Palladium-catalyzed carboxylation of allyl stannanes
    Shi, M
    Nicholas, KM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (21) : 5057 - 5058
  • [43] PALLADIUM CATALYZED ALLYLATION OF NITROALKANES WITH ALLYL CHLORIDES
    ALEKSANDROWICZ, P
    PIOTROWSKA, H
    SAS, W
    [J]. MONATSHEFTE FUR CHEMIE, 1982, 113 (10): : 1221 - 1224
  • [44] SYNTHESIS OF DIENOIC ACIDS AND ESTERS BY CATIONIC PALLADIUM COMPLEX-CATALYZED CARBONYLATION OF ALKYNOLS AND ALKYNEDIOLS
    HUH, KT
    ORITA, A
    ALPER, H
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (25): : 6956 - 6957
  • [45] RHODIUM COMPLEX CATALYZED METHANOL CARBONYLATION
    HJORTKJAER, J
    JENSEN, VW
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1976, 15 (01): : 46 - 49
  • [46] Palladium-Catalyzed Amination of Allyl Alcohols
    Ghosh, Raju
    Sarkar, Amitabha
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (20): : 8508 - 8512
  • [47] REACTIONS OF HEXAMETHYLDISTANNANE WITH ALLYL ACETATES AND ALLYL HALIDES CATALYZED BY PALLADIUM COMPLEXES
    BUMAGIN, NA
    KASATKIN, AN
    BELETSKAYA, IP
    [J]. BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1984, 33 (03): : 588 - 594
  • [48] N-heterocyclic carbene-palladium complex catalyzed oxidative carbonylation of amines to ureas
    Zheng Shu-Zhan
    Peng Xin-Gao
    Liu Jian-Ming
    Sun Wei
    Xia Chun-Gu
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (08) : 1065 - 1068
  • [49] Palladium-catalyzed carbonylation of aryl tosylates and mesylates
    Munday, Rachel H.
    Martinelli, Joseph R.
    Buchwald, Stephen L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (09) : 2754 - +
  • [50] DESULFONYLATIVE CARBONYLATION OF ARYLSULFONYL CHLORIDES CATALYZED BY PALLADIUM COMPLEXES
    ITOH, K
    HASHIMOTO, H
    MIURA, M
    NOMURA, M
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1990, 59 (03): : 325 - 332
12345