PALLADIUM-COMPLEX-CATALYZED DECARBOXYLATION CARBONYLATION OF ALLYL DIETHYLCARBAMATES

被引：0
|
作者：
MIYAZAWA, M [1 ]
WANG, SZ [1 ]
TAKEDA, H [1 ]
YAMAMOTO, K [1 ]
机构：
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN
来源：
SYNLETT | 1992年 / 04期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diethylcarbamic acid allylic esters 1 undergo decarboxylation-carbonylation to give the corresponding beta,gamma-unsaturated amides 2 under rather forcing conditions [CO (50-80 atm) at 100-degrees-C] in the presence of a palladium(0)-triphenylphosphine complex as catalyst.
引用
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页码：323 / 324
页数：2
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