PALLADIUM-COMPLEX-CATALYZED DECARBOXYLATION CARBONYLATION OF ALLYL DIETHYLCARBAMATES

被引：0
|
作者：
MIYAZAWA, M [1 ]
WANG, SZ [1 ]
TAKEDA, H [1 ]
YAMAMOTO, K [1 ]
机构：
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN
来源：
SYNLETT | 1992年 / 04期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diethylcarbamic acid allylic esters 1 undergo decarboxylation-carbonylation to give the corresponding beta,gamma-unsaturated amides 2 under rather forcing conditions [CO (50-80 atm) at 100-degrees-C] in the presence of a palladium(0)-triphenylphosphine complex as catalyst.
引用
收藏
页码：323 / 324
页数：2
相关论文
共 50 条
  • [1] KINETICS ON PALLADIUM CATALYZED CARBONYLATION OF ALLYL CHLORIDE PRESSURE
    YOSHIDA, H
    SUGITA, N
    KUDO, K
    TAKEZAKI, Y
    [J]. NIPPON KAGAKU KAISHI, 1974, (06) : 1002 - 1008
  • [2] Palladium-catalyzed carbonylation of allyl alcohols in the presence of phenols
    Satoh, T
    Ikeda, M
    Kushino, Y
    Miura, M
    Nomura, M
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (08): : 2662 - 2664
  • [3] Synthesis of 1,4-enyne-3-ones via palladium-catalyzed sequential decarboxylation and carbonylation of allyl alkynoates
    Li, Zun
    Zheng, Jia
    Hu, Weigao
    Li, Jianxiao
    Wu, Wanqing
    Jiang, Huanfeng
    [J]. ORGANIC CHEMISTRY FRONTIERS, 2017, 4 (07): : 1363 - 1366
  • [4] Palladium-catalyzed allylation and carbonylation: access to allylhydrazones and allyl acylhydrazones
    Liang, Qianqian
    Cai, Yan
    Jiang, Wenjun
    Pang, Mengdi
    Fan, Liming
    Zhang, Guoying
    [J]. CHEMICAL COMMUNICATIONS, 2024, 60 (12) : 1638 - 1641
  • [5] Palladium-complex-catalyzed cyanation of allylic carbonates and acetates using trimethylsilyl cyanide
    Tsuji, Y
    Kusui, T
    Kojima, T
    Sugiura, Y
    Yamada, N
    Tanaka, S
    Ebihara, M
    Kawamura, T
    [J]. ORGANOMETALLICS, 1998, 17 (22) : 4835 - 4841
  • [6] SOME ASPECTS ON MECHANISM OF PALLADIUM-COMPLEX-CATALYZED DECOMPOSITION OF AND CYCLOPROPANATION WITH ETHYL DIAZOACETATE
    NAKAMURA, A
    KOYAMA, T
    OTSUKA, S
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (02) : 593 - 595
  • [7] CARBONYLATION OF STYRENE CATALYZED BY A PALLADIUM-BIPHOSPHINE COMPLEX
    SUGI, Y
    BANDO, K
    SHIN, S
    [J]. CHEMISTRY & INDUSTRY, 1975, (09) : 397 - 398
  • [8] Palladium-Catalyzed Carbonylation of Aryl, Alkenyl, and Allyl Halides with Phenyl Formate
    Ueda, Tsuyoshi
    Konishi, Hideyuki
    Manabe, Kei
    [J]. ORGANIC LETTERS, 2012, 14 (12) : 3100 - 3103
  • [9] PALLADIUM CATALYZED TEMPLATE REACTIONS - COUPLING-CARBONYLATION OF ACETYLENE AND ALLYL ALCOHOL
    INTILLE, GM
    BECK, GR
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, 170 (AUG24): : 31 - 31
  • [10] DFT computational study of the mechanism of allyl chloride carbonylation catalyzed by palladium complexes
    Carvajal, MA
    Miscione, GP
    Novoa, JJ
    Bottoni, A
    [J]. ORGANOMETALLICS, 2005, 24 (09) : 2086 - 2096
12345